Here are listed the appearances of antagonists of Pokémon Adventures. The characters within the villainous teams are in the order of their first appearance.

Team Rocket

Koga

Note: Has become good to join the Jhoto Elite Four.

PS007 - Raging Rhydon
PS014 - That Awful Arbok!
PS023 - Make Way For Magmar! (flashback)
PS026 - Holy Moltres
PS029 - Go for the Golbat
PS031 - The Art of Articuno
PS032 - A Little Kadabra'll Do It (flashback)
PS035 - And Mewtwo... Three! (fantasy)
PS038 - Long Live the Nidoqueen?! (flashback)
PS056 - The Coming of Slowpoke (Eventually) (fantasy)
PS065 - Karate Machop!
PS066 - Punching Poliwrath
PS069 - Playing Horsea
PS070 - Allied by Alakazam!
PS071 - Muk Raking
PS072 - Weezing Winks Out
PS076 - Take a Chance on Chansey
PS077 - Striking Golduck
PS085 - Gimme Shellder
PS099 - Sunkern Treasure (silhouette)
PS136 - Crossing Crobat (flashback)
PS156 - Notorious Noctowl (flashback)
PS168 - The Last Battle II (flashback)
PS175 - The Last Battle IX (silhouette)
PS176 - The Last Battle X
PS180 - The Last Battle XIV
PS443 - Attaway, Aipom!
PS444 - One Tough Togepi
PS459 - All About Arceus VIII (flashback)
PS460 - All About Arceus IX

Lt. Surge

Note: Has become good to be a Gym Leader once again.

PS010 - Danger: High Voltorb
PS011 - Buzz Off, Electabuzz!
PS023 - Make Way For Magmar! (flashback)
PS026 - Holy Moltres
PS028 - Peace of Mime
PS029 - Go for the Golbat
PS030 - Zap! Zap! Zapdos!
PS032 - A Little Kadabra'll Do It (flashback)
PS035 - And Mewtwo... Three! (fantasy)
PS037 - Golly, Golem! (flashback)
PS038 - Long Live the Nidoqueen?! (flashback)
PS056 - The Coming of Slowpoke (Eventually) (fantasy)
PS065 - Karate Machop!
PS066 - Punching Poliwrath
PS069 - Playing Horsea
PS070 - Allied by Alakazam!
PS074 - Make Way for Magikarp
PS075 - Electrode's Big Shock!
PS078 - Victim of Venusaur
PS084 - Clefabulous Clefable
PS085 - Gimme Shellder
PS090 - The Legend
PS099 - Sunkern Treasure (picture)
PS121 - Off Course with Corsola
PS139 - Raising Raichu
PS140 - Do-Si-Do with Dodrio
PS141 - Hello, Lickitung
PS142 - Really Remoraid
PS145 - Sandslash Surprise
PS146 - Lively Lugia I
PS147 - Lively Lugia II
PS149 - Curious Kingdra
PS150 - Chinchou in Charge
PS154 - Yikes, It's Yanma!
PS155 - Capital Kabutops
PS156 - Notorious Noctowl
PS157 - Magnificent Magnemite
PS158 - Silly Scyther
PS163 - Bringing up Bellossom (flashback)
PS165 - Lugia and Ho-Oh on the Loose (Part 1)
PS168 - The Last Battle II
PS169 - The Last Battle III
PS170 - The Last Battle IV
PS171 - The Last Battle V
PS178 - The Last Battle XII
PS180 - The Last Battle XIV
PS448 - Pleased as Punch With Parasect (flashback)

Blaine

Note: Has become good after Mewtwo escaped.

PS016 - Tauros the Tyrant
PS026 - Holy Moltres
PS032 - A Little Kadabra'll Do It (flashback)
PS034 - And Mewtwo Too?!
PS035 - And Mewtwo... Three!
PS047 - Purrrr-sian
PS048 - Paras Sight
PS049 - As Gastly as Before
PS055 - The Primate Directive
PS064 - Putting It on the Line...Against Arcanine
PS065 - Karate Machop!
PS066 - Punching Poliwrath
PS069 - Playing Horsea
PS070 - Allied by Alakazam!
PS074 - Make Way for Magikarp
PS075 - Electrode's Big Shock!
PS078 - Victim of Venusaur
PS079 - Airing Out Aerodactyl
PS080 - Draggin' In Dragonair
PS081 - Aerodactyl Redux
PS082 - Eradicate Raticate! (flashback)
PS085 - Gimme Shellder
PS090 - The Legend
PS154 - Yikes, It's Yanma!
PS155 - Capital Kabutops
PS161 - Entranced by Entei
PS162 - Heckled by Hitmontop
PS163 - Bringing up Bellossom (flashback)
PS165 - Lugia and Ho-Oh on the Loose (Part 1)
PS168 - The Last Battle II
PS169 - The Last Battle III
PS170 - The Last Battle IV
PS171 - The Last Battle V
PS178 - The Last Battle XII
PS180 - The Last Battle XIV
PS295 - Double Down Deoxys

Ken

PS016 - Tauros the Tyrant
PS017 - The Jynx Jinx
PS020 - Meanwhile...Vileplume! (flashback)
PS056 - The Coming of Slowpoke (Eventually)
PS057 - Ekans the Ecstasy
PS093 - Sneasel Sneak Attack
PS094 - Elekid Incorporated
PS100 - Into the Unown
PS110 - Piloswine Whine (flashback)
PS128 - Indubitably Ditto
PS129 - Great Girafarig
PS153 - Oh, It's Ho-Oh!
PS168 - The Last Battle II
PS296 - It's Starting to Make Sense Now (flashback)
PS457 - All About Arceus VI
PS458 - All About Arceus VII (flashback)
PS460 - All About Arceus IX

Sabrina

Note: Has become good to be a Gym Leader again and a Movie Star.

PS020 - Meanwhile...Vileplume!
PS026 - Holy Moltres
PS027 - Kalling Kadabra
PS030 - Zap! Zap! Zapdos!
PS032 - A Little Kadabra'll Do It
PS033 - The Winged Legends
PS035 - And Mewtwo... Three! (fantasy)
PS038 - Long Live the Nidoqueen?! (flashback)
PS056 - The Coming of Slowpoke (Eventually) (fantasy)
PS065 - Karate Machop!
PS066 - Punching Poliwrath
PS069 - Playing Horsea
PS070 - Allied by Alakazam!
PS073 - Valiant Venomoth!
PS083 - Bang the Drum, Slowbro
PS084 - Clefabulous Clefable
PS089 - The Might of... Metapod?!
PS090 - The Legend
PS099 - Sunkern Treasure (picture)
PS123 - Debonaire Dragonair (fantasy)
PS139 - Raising Raichu
PS150 - Chinchou in Charge
PS154 - Yikes, It's Yanma!
PS155 - Capital Kabutops
PS156 - Notorious Noctowl
PS157 - Magnificent Magnemite
PS158 - Silly Scyther
PS163 - Bringing up Blossom (flashback)
PS165 - Lugia and Ho-Oh on the Loose (Part 1)
PS168 - The Last Battle II (flashback)
PS175 - The Last Battle IX
PS180 - The Last Battle XIV
PS330 - The Final Battle III (flashback)
PS530

Giovanni

PS023 - Make Way For Magmar!
PS026 - Holy Moltres
PS033 - The Winged Legends
PS036 - Drat That Dratini!
PS037 - Golly, Golem!
PS038 - Long Live the Nidoqueen?!
PS056 - The Coming of Slowpoke (Eventually) (fantasy)
PS067 - Can You Diglett? (fantasy)
PS068 - Jigglypuff Jive
PS087 - Rhyhorn Rising
PS088 - The Beedrill All and End All
PS089 - The Might of... Metapod?!
PS090 - The Legend
PS099 - Sunkern Treasure (silhouette)
PS139 - Raising Raichu (flashback)
PS162 - Heckled by Hitmontop (fantasy)
PS167 - The Last Battle I (flashback)
PS168 - The Last Battle II (flashback)
PS176 - The Last Battle X (flashback)
PS267 - It All Ends Now VIII
PS276 - My, My, My Mimic (fantasy)
PS277 - A Beastly Cold Reception (fantasy)
PS280 - Some Things Are Better Left Unown
PS281 - Not Exactly Normal
PS282 - Going Green
PS283 - It Takes Patience, Knowledge and a Really Quick Beedrill
PS286 - Meet Deoxys, and Deoxys, and Deoxys, and...
PS287 - Secrets from Sneasel
PS288 - Give It Your Best, Blastoise
PS289 - Surprised by Sneasel
PS290 - A Well-Journeyed Jumpluff
PS291 - Can Mewtwo Dish It Out with a Spoon?
PS292 - Bested by Banette
PS293 - Down-for-the-Count Deoxys
PS294 - Mewtwo and Mew Too
PS295 - Double Down Deoxys
PS296 - It's Starting to Make Sense Now
PS297 - Mewtwo Comes Through
PS298 - Start the Countdown, Starmie
PS299 - Distant Relation Deoxys (flashback)
PS300 - Right on Time, Rhydon
PS301 - Storming the Forretress
PS445 - Dealing With A Koffing Fit (flashback)
PS446 - Weavile Wobbles But It Won't Fall Down (flashback)
PS447 - Fortunately for Feraligatr (flashback)
PS449 - Raising the Stakes with Rhyperior (flashback)
PS455 - All About Arceus IV (fantasy)
PS456 - All About Arceus V
PS457 - All About Arceus VI
PS458 - All About Arceus VII
PS459 - All About Arceus VIII
PS460 - All About Arceus IX
PAORAS05 (flashback)
PAORAS17
PAORAS18
PAORAS20
PAORAS21

Harry

PS025 - You Know...Articuno!
PS056 - The Coming of Slowpoke (Eventually)
PS057 - Ekans the Ecstasy
PS093 - Sneasel Sneak Attack
PS094 - Elekid Incorporated
PS100 - Into the Unown
PS128 - Indubitably Ditto
PS129 - Great Girafarig
PS131 - Suddenly Suicune II
PS153 - Oh, It's Ho-Oh!
PS168 - The Last Battle II
PS296 - It's Starting to Make Sense Now (flashback)
PS457 - All About Arceus VI
PS458 - All About Arceus VII (flashback)
PS460 - All About Arceus IX

Al

PS026 - Holy Moltres
PS056 - The Coming of Slowpoke (Eventually)
PS057 - Ekans the Ecstasy
PS093 - Sneasel Sneak Attack
PS094 - Elekid Incorporated
PS100 - Into the Unown
PS110 - Piloswine Whine (flashback)
PS128 - Indubitably Ditto
PS129 - Great Girafarig
PS153 - Oh, It's Ho-Oh!
PS168 - The Last Battle II
PS296 - It's Starting to Make Sense Now (flashback)
PS457 - All About Arceus VI
PS458 - All About Arceus VII (flashback)
PS460 - All About Arceus IX

Masked Man

Note: Is no longer evil in his true identity.

PS103 - You Ain't Nothin' but a Houndour
PS104 - The Ariados up There
PS112 - Raise the Red Gyarados
PS113 - Delibird Delivery - 1
PS114 - Delibird Delivery - 2
PS127 - Miltank Melee
PS132 - Suddenly Suicune III
PS139 - Raising Raichu
PS140 - Do-Si-Do with Dodrio (flashback)
PS142 - Really Remoraid
PS145 - Sandslash Surprise (flashback)
PS146 - Lively Lugia I (flashback)
PS156 - Notorious Noctowl (flashback)
PS157 - Magnificent Magnemite (flashback)
PS159 - Popular Pupitar (flashback and fantasy)
PS160 - Playful Porygon2 (flashback)
PS162 - Heckled by Hitmontop (flashback)
PS163 - Bringing up Bellossom (screen)
PS164 - Slick Slowking
PS165 - Lugia and Ho-Oh on the Loose (Part 1)
PS166 - Lugia and Ho-Oh on the Loose (Part 2)
PS167 - The Last Battle I
PS170 - The Last Battle IV
PS171 - The Last Battle V
PS172 - The Last Battle VI (true identity is revealed)
PS174 - The Last Battle VIII (flashback)
PS268 - The Escape (flashback)
PS297 - Mewtwo Comes Through (flashback)

Carl

PS110 - Piloswine Whine
PS113 - Delibird Delivery - 1 (silhouette)
PS132 - Suddenly Suicune III
PS153 - Oh, It's Ho-Oh!
PS159 - Popular Pupitar (silhouette)
PS163 - Bringing up Bellossom
PS164 - Slick Slowking
PS165 - Lugia and Ho-Oh on the Loose (Part 1)
PS174 - The Last Battle VIII (flashback)
PS179 - The Last Battle XIII
PS268 - The Escape (flashback)
PS297 - Mewtwo Comes Through (flashback)

Sham

PS110 - Piloswine Whine
PS113 - Delibird Delivery - 1 (silhouette)
PS132 - Suddenly Suicune III
PS153 - Oh, It's Ho-Oh!
PS159 - Popular Pupitar (silhouette)
PS163 - Bringing up Bellossom
PS164 - Slick Slowking
PS174 - The Last Battle VIII (flashback)
PS179 - The Last Battle XIII
PS268 - The Escape (flashback)
PS297 - Mewtwo Comes Through (flashback)

Will

Note: Has become good to join the Jhoto Elite Four.

PS113 - Delibird Delivery - 1 (silhouette)
PS159 - Popular Pupitar (silhouette)
PS173 - The Last Battle VII
PS174 - The Last Battle VIII
PS177 - The Last Battle XI
PS180 - The Last Battle XIV
PS268 - The Escape (flashback)
PS297 - Mewtwo Comes Through (flashback)
PS443 - Attaway, Aipom!
PS444 - One Tough Togepi
PS459 - All About Arceus VIII (flashback)
PS460 - All About Arceus IX

Karen

Note: Has become good to join the Jhoto Elite Four.

PS113 - Delibird Delivery - 1 (silhouette)
PS159 - Popular Pupitar (silhouette)
PS173 - The Last Battle VII
PS174 - The Last Battle VIII
PS176 - The Last Battle X
PS177 - The Last Battle XI
PS180 - The Last Battle XIV
PS268 - The Escape (flashback)
PS297 - Mewtwo Comes Through (flashback)
PS443 - Attaway, Aipom!
PS444 - One Tough Togepi
PS447 - Fortunately for Feraligatr (flashback)
PS459 - All About Arceus VIII (flashback)
PS460 - All About Arceus IX

Carr

PS277 - A Beastly Cold Reception
PS278 - Put Your Beast Foot Forward
PS279 - Don't Doubt Deoxys
PS281 - Not Exactly Normal
PS282 - Going Green
PS283 - It Takes Patience, Knowledge and a Really Quick Beedrill
PS286 - Meet Deoxys, and Deoxys, and Deoxys, and...
PS287 - Secrets from Sneasel
PS288 - Give It Your Best, Blastoise
PS296 - It's Starting to Make Sense Now (flashback)
PS297 - Mewtwo Comes Through
PS298 - Start the Countdown, Starmie
PS445 - Dealing With A Koffing Fit
PS456 - All About Arceus V (flashback)
PAORAS05 (flashback)

Orm

PS277 - A Beastly Cold Reception
PS278 - Put Your Beast Foot Forward
PS279 - Don't Doubt Deoxys
PS282 - Going Green (flashback)
PS286 - Meet Deoxys, and Deoxys, and Deoxys, and...
PS287 - Secrets from Sneasel
PS288 - Give It Your Best, Blastoise
PS289 - Surprised by Sneasel
PS290 - A Well-Journeyed Jumpluff
PS292 - Bested by Banette
PS293 - Down-for-the-Count Deoxys
PS296 - It's Starting to Make Sense Now
PS297 - Mewtwo Comes Through
PS298 - Start the Countdown, Starmie
PS445 - Dealing With A Koffing Fit (flashback)
PAORAS05 (flashback)

Archer

PS445 - Dealing With A Koffing Fit
PS450 - With a Little Help From Hitmonchan
PS451 - It Takes Xatu to Tango
PS454 - All About Arceus III
PS455 - All About Arceus IV
PS456 - All About Arceus V
PS457 - All About Arceus VI
PS458 - All About Arceus VII
PS460 - All About Arceus IX

Ariana

PS445 - Dealing With A Koffing Fit
PS448 - Pleased as Punch With Parasect
PS449 - Raising the Stakes with Rhyperior
PS450 - With a Little Help From Hitmonchan
PS451 - It Takes Xatu to Tango
PS452 - All About Arceus I (fantasy)
PS454 - All About Arceus III
PS455 - All About Arceus IV
PS456 - All About Arceus V
PS457 - All About Arceus VI
PS458 - All About Arceus VII
PS460 - All About Arceus IX

Petrel

PS445 - Dealing With A Koffing Fit
PS446 - Weavile Wobbles But It Won't Fall Down
PS447 - Fortunately for Feraligatr
PS450 - With a Little Help From Hitmonchan
PS451 - It Takes Xatu to Tango
PS452 - All About Arceus I (fantasy)
PS454 - All About Arceus III
PS455 - All About Arceus IV
PS456 - All About Arceus V
PS457 - All About Arceus VI
PS458 - All About Arceus VII
PS460 - All About Arceus IX

Proton

PS445 - Dealing With A Koffing Fit
PS447 - Fortunately for Feraligatr
PS450 - With a Little Help From Hitmonchan
PS451 - It Takes Xatu to Tango
PS454 - All About Arceus III
PS455 - All About Arceus IV
PS456 - All About Arceus V
PS457 - All About Arceus VI
PS458 - All About Arceus VII
PS460 - All About Arceus IX

Kanto Elite Four

See User:Super10ZX/Appearances of Pokémon Adventures Characters/Elite Four

Team Aqua

Archie

PS188 - Lombre Larceny
PS189 - Mowing Down Ludicolo
PS192 - Stick This in Your Craw, Crawdaunt I
PS214 - Assaulted by Pelipper I
PS219 - What Would You Do for a Whismur? (fantasy)
PS225 - Tanks, but No Tanks, Anorith & Lileep
PS230 - Walrein and Camerupt
PS231 - Master Class with Masquerain
PS232 - Always Keep Whiscash on You for Emergencies
PS233 - The Beginning of the End with Kyogre & Groudon I
PS234 - The Beginning of the End with Kyogre & Groudon II
PS242 - Very Vexing Volbeat
PS243 - No Armaldo Is an Island
PS244 - The Beginning of the End with Kyogre & Groudon VIII (flashback)
PS248 - The Beginning of the End with Kyogre & Groudon X
PS249 - The Beginning of the End with Kyogre & Groudon XI
PS250 - The Beginning of the End with Kyogre & Groudon XII
PS252 - The Beginning of the End with Kyogre & Groudon XIV
PS257 - The Beginning of the End with Kyogre & Groudon XV (flashback)
PS264 - It All Ends Now V
PS265 - It All Ends Now VI
PS266 - It All Ends Now VII
PS267 - It All Ends Now VIII
PS327 - Facing Gulpin Is Hard to Swallow (Identity as Guile Hideout is revealed)
PS328 - The Final Battle I
PS329 - The Final Battle II
PS333 - The Final Battle VI
PS334 - The Final Battle VII
PS335 - The Final Battle VIII
PS336 - The Final Battle IX
PAORAS05 (fantasy)
PAORAS10
PAORAS11
PAORAS12
PAORAS14 (flashback)
PAORAS16
PAORAS17
PAORAS18