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The name currently in use is a fan designator; see below for more information.
Mallow's brother is the older brother of Mallow and the son of Abe.
In the anime
Mallow's brother appeared in a flashback in A Seasoned Search!, where it was revealed that he is currently traveling around the world to become a better chef with a Lickitung. During his journey, he discovered an old recipe describing how to make Alolan Stew and sent it to his younger sister, Mallow.
In the games
Mallow's brother is a chef who works at the restaurant in Konikoni City. In Pokémon Moon, after defeating Olivia, the player can visit Mallow in her room on the second floor of the restaurant. Mallow asks the player to meet them in Lush Jungle for a battle and leaves, but before the player can follow they are asked by Mallow's brother to look for his Wimpod, who was gathering ingredients for the restaurant in Lush Jungle. After defeating Mallow, she finds her brother's Wimpod, and the player and her return to the restaurant. In Pokémon Sun this sidequest cannot be activated but Mallow's brother can be found on the second floor of the restaurant, stating he hopes Mallow and the player will stay friends.