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The Masters Battle is a match type in Pokémon Battle Revolution held in Stargazer Colosseum, after the player wins the Pokétopia Championship. The Masters Battle consists of eight sets of four Trainers, with a Colosseum Master heading each set. All the Trainers in the Masters Battle use highly advanced combinations and tactics, and may need a specific approach to defeat. Initially, only Set 1 will be unlocked. The player must beat each Set to unlock the next Set and can re-challenge any unlocked Set at anytime. On a side note, Mysterial's team, who appear heading Sets 4 and 8, changes depending on the game used to transfer Pokémon into Pokémon Battle Revolution.

Intelligence in a CPU Trainer has never before been seen on a level such as this. All battles may need to be approached from a different angle in order to win. Above all, none of the Masters Battle Trainers are to be taken lightly.

The list below contains all known Pokémon, moves, items and abilities used by each trainer in Masters Battle - Sets 1 though 4.

Set 1

Battle One

[[Master Class (Trainer class)|Master Class]] Chance [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution [[Master Class (Trainer class)|Master Class]] and Professor Chance Oak [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution Reward: None

Types: Bug Ground Ability: Anticipation Held item: Quick Claw Wormadam♀ Lv.50 Earthquake Ground Physical   --       Fissure Ground Physical   --       Unknown Unknown   --       Unknown Unknown   --       Types: Bug Flying Ability: Swarm Held item: Power Herb Beautifly♀ Lv.50 Psychic Psychic Special   --       SolarBeam Grass Special   --       Bug Buzz Bug Special   --       Unknown Unknown   --       Types: Bug Poison Ability: Shield Dust Held item: Leftovers Dustox♀ Lv.50 Silver Wind Bug Special   --       Light Screen Psychic Status   --       Toxic Poison Status   --       Protect Normal Status   --       Types: Bug Unknown Ability: Swarm Held item: None Kricketune♀ Lv.50 X-Scissor Bug Physical   --       Perish Song Normal Status   --       Substitute Normal Status   --       Unknown Unknown   --       Types: Bug Flying Ability: Swarm Held item: Focus Sash Mothim♀ Lv.50 Bug Buzz Bug Special   --       Energy Ball Grass Special   --       Unknown Unknown   --       Unknown Unknown   --       Types: Bug Flying Ability: Pressure Held item: Charti Berry Vespiqueen♀ Lv.50 Attack Order Bug Physical   --       Defend Order Bug Status   --       Heal Order Bug Status   --       Unknown Unknown   --

Battle Two

[[Master Class (Trainer class)|Master Class]] Kerry [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution [[Master Class (Trainer class)|Master Class]] and Professor Kerry Oak [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution Reward: None

Types: Fighting Psychic Ability: Pure Power Held item: None Medicham♀ Lv.50 Fake Out Normal Physical   --       Hi Jump Kick Fighting Physical   --       Unknown Unknown   --       Unknown Unknown   --       Types: Fighting Unknown Ability: No Guard Held item: None Machamp♂ Lv.50 DynamicPunch Fighting Physical   --       Protect Normal Status   --       Fling Dark Physical   --       Unknown Unknown   --       Types: Normal Unknown Ability: Klutz Held item: Flame Orb Lopunny♀ Lv.50 Bounce Normal Physical   --       Dizzy Punch Normal Physical   --       Fling Dark Physical   --       Unknown Unknown   --       Types: Water Ground Ability: No Ability Held item: Earth Plate Quagsire♀ Lv.50 Fling Dark Physical   --       Earthquake Ground Physical   --       Protect Normal Status   --       Unknown Unknown   --       Types: Water Flying Ability: Keen Eye Held item: King's Rock Pelipper♂ Lv.50 Fling Dark Physical   --       Water Pulse Water Special   --       Tailwind Flying Status   --       Roost Flying Status   --       Types: Rock Unknown Ability: Rock Head Held item: Hard Stone Sudowoodo♀ Lv.50 Fling Dark Physical   --       Wood Hammer Grass Physical   --       Stone Edge Rock Physical   --       Protect Normal Status   --

Semifinal

[[Joe's Groupie (Trainer class)|Joe's Groupie]] Kelsey [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution [[Joe's Groupie (Trainer class)|Joe's Groupie]] and Professor Kelsey Oak [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution Reward: None

Types: Normal Unknown Ability: No Ability Held item: None Purugly♀ Lv.50 Fake Out Normal Physical   --       Slash Normal Physical   --       Aerial Ace Flying Physical   --       Shadow Claw Ghost Physical   --       Types: Ghost Flying Ability: Unburden Held item: Lum Berry Drifblim♂ Lv.50 Charge Beam Electric Special   --       Destiny Bond Ghost Status   --       Psychic Psychic Special   --       Unknown Unknown   --       Types: Psychic Unknown Ability: No Ability Held item: None Mr. Mime♂ Lv.50 Psychic Psychic Special   --       Focus Blast Fighting Special   --       Safeguard Normal Status   --       Energy Ball Grass Special   --       Types: Electric Unknown Ability: Intimidate Held item: Persim Berry Luxray♂ Lv.50 Thunder Fang Electric Physical   --       Ice Fang Ice Physical   --       Iron Tail Steel Physical   --       Unknown Unknown   --       Types: Normal Psychic Ability: No Ability Held item: Sitrus Berry Girafarig♀ Lv.50 Swagger Normal Status   --       Reflect Normal Status   --       Unknown Unknown   --       Unknown Unknown   --       Types: Electric Unknown Ability: No Ability Held item: None Pachirisu♀ Lv.50 Super Fang Normal Physical   --       Flatter Normal Status   --       Unknown Unknown   --       Unknown Unknown   --

Final

[[Master Junior (Trainer class)|Master Junior]] Joe [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution [[Master Junior (Trainer class)|Master Junior]] and Professor Joe Oak [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution Reward: None

Types: Fire Fighting Ability: Blaze Held item: None Infernape♂ Lv.50 Focus Blast Fighting Special   --       Heat Wave Fire Special   --       Protect Normal Status   --       Shadow Claw Ghost Physical   --       Types: Grass Ground Ability: Overgrow Held item: Yache Berry Torterra♀ Lv.50 Seed Bomb Grass Physical   --       Earthquake Ground Physical   --       Unknown Unknown   --       Unknown Unknown   --       Types: Water Steel Ability: Torrent Held item: None Empoleon♀ Lv.50 Surf Water Special   --       Ice Beam Ice Special   --       Unknown Unknown   --       Unknown Unknown   --       Types: Electric Unknown Ability: Static Held item: Light Ball Pikachu♂ Lv.50 Volt Tackle Electric Physical   --       Iron Tail Steel Physical   --       Protect Normal Status   --       Unknown Unknown   --       Types: Normal Unknown Ability: No Ability Held item: None Aipom♀ Lv.50 Thunder Wave Electric Status   --       Protect Normal Status   --       Fury Swipes Normal Physical   --       Unknown Unknown   --       Types: Normal Flying Ability: Intimidate Held item: Focus Sash Staraptor♀ Lv.50 Return Normal Physical   --       Protect Normal Status   --       Pluck Flying Physical   --       Unknown Unknown   --

Set 2

Battle One

[[Master Class (Trainer class)|Master Class]] Erica [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution [[Master Class (Trainer class)|Master Class]] and Professor Erica Oak [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution Reward: None

Types: Normal Flying Ability: No Ability Held item: None Noctowl♀ Lv.50 Hypnosis Psychic Status   --       Swagger Normal Status   --       Double Team Normal Status   --       Roost Flying Status   --       Types: Grass Unknown Ability: Levitate Held item: None Carnivine♀ Lv.50 Leech Seed Grass Status   --       Protect Normal Status   --       Stockpile Normal Status   --       Unknown Unknown   --       Types: Grass Poison Ability: No Ability Held item: None Roserade♂ Lv.50 Giga Drain Grass Special   --       Toxic Spikes Poison Status   --       Unknown Unknown   --       Unknown Unknown   --       Types: Steel Ground Ability: No Ability Held item: None Steelix♀ Lv.50 Stealth Rock Rock Status   --       Roar Normal Status   --       Unknown Unknown   --       Unknown Unknown   --       Types: Normal Unknown Ability: Klutz Held item: Toxic Orb Lopunny♀ Lv.50 Switcheroo Normal Status   --       Substitute Normal Status   --       Attract Normal Status   --       Unknown Unknown   --       Types: Normal Unknown Ability: No Ability Held item: Leftovers Blissey♀ Lv.50 Water Pulse Water Special   --       Heal Bell Normal Status   --       Stealth Rock Rock Status   --       Unknown Unknown   --

Battle Two

[[Master Class (Trainer class)|Master Class]] Jaden [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution [[Master Class (Trainer class)|Master Class]] and Professor Jaden Oak [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution Reward: None

Types: Poison Dark Ability: No Ability Held item: Shuca Berry Drapion♂ Lv.50 Night Slash Dark Physical   --       Acupressure Normal Status   --       Protect Normal Status   --       Unknown Unknown   --       Types: Normal Water Ability: Simple Held item: None Bibarel♀ Lv.50 Super Fang Normal Physical   --       Protect Normal Status   --       Waterfall Water Physical   --       Unknown Unknown   --       Types: Water Poison Ability: Clear Body Held item: Focus Sash Tentacruel♂ Lv.50 Hydro Pump Water Special   --       Acupressure Normal Status   --       Protect Normal Status   --       Unknown Unknown   --       Types: Normal Unknown Ability: No Ability Held item: None Ambipom♀ Lv.50 Double Hit Normal Physical   --       Unknown Unknown   --       Unknown Unknown   --       Unknown Unknown   --       Types: Water Unknown Ability: No Ability Held item: Focus Band Seaking♀ Lv.50 Surf Water Special   --       Horn Drill Normal Physical   --       Protect Normal Status   --       Megahorn Bug Physical   --       Types: Psychic Unknown Ability: Levitate Held item: None Chimecho♀ Lv.50 Psychic Psychic Special   --       Hypnosis Psychic Special   --       Protect Normal Status   --       Shadow Ball Ghost Special   --

Semifinal

[[Sashay Fan Club (Trainer class)|Sashay Fan Club]] Joy [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution [[Sashay Fan Club (Trainer class)|Sashay Fan Club]] and Professor Joy Oak [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution Reward: None

Types: Poison Flying Ability: Inner Focus Held item: Black Sludge Crobat♀ Lv.50 Confuse Ray Ghost Status   --       Mean Look Normal Status   --       Double Team Normal Status   --       Unknown Unknown   --       Types: Water Unknown Ability: Marvel Scale Held item: Leftovers Milotic♀ Lv.50 Wrap Normal Status   --       Recover Normal Status   --       Toxic Poison Status   --       Confuse Ray Ghost Status   --       Types: Water Unknown Ability: No Ability Held item: None Golduck♂ Lv.50 Hydro Pump Water Special   --       Disable Normal Status   --       Protect Normal Status   --       Toxic Poison Status   --       Types: Water Flying Ability: Keen Eye Held item: Focus Sash Pelipper♀ Lv.50 Tailwind Flying Status   --       Swagger Normal Status   --       Unknown Unknown   --       Unknown Unknown   --       File:421b.png Types: Grass Unknown Ability: Flower Gift Held item: Occa Berry Cherrim♀ Lv.50 Toxic Poison Status   --       Leech Seed Grass Status   --       Protect Normal Status   --       Double Team Normal Status   --       Types: Fire Unknown Ability: Flash Fire Held item: None Rapidash♀ Lv.50 Fire Blast Fire Special   --       Bounce Normal Physical   --       Attract Normal Status   --       Toxic Poison Status   --

Final

[[Master Middle (Trainer class)|Master Middle]] Sashay [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution [[Master Middle (Trainer class)|Master Middle]] and Professor Sashay Oak [[Stargazer Colosseum|Stargazer Colosseum]] Pokémon Battle Revolution Reward: None

Types: Electric Unknown Ability: Static Held item: None Raichu♀ Lv.50 Fake Out Normal Physical   --       Discharge Electric Special   --       Double Team Normal Status   --       Swagger Normal Status   --       Types: Ghost Poison Ability: Levitate Held item: None Gengar♀ Lv.50 Spite Ghost Status   --       Protect Normal Status   --       Unknown Unknown   --       Unknown Unknown   --       Types: Dark Ice Ability: Pressure Held item: None Weavile♀ Lv.50 Protect Normal Status   --       Spite Ghost Status   --       Substitute Normal Status   --       Swagger Normal Status   --       Types: Ghost Unknown Ability: Levitate Held item: None Mismagius♀ Lv.50 Protect Normal Status   --       Confuse Ray Normal Status   --       Double Team Normal Status   --       Unknown Unknown   --       Types: Bug Flying Ability: Pressure Held item: Quick Claw Vespiquen♀ Lv.50 Protect Normal Status   --       Double Team Normal Status   --       Attack Order Bug Physical   --       Unknown Unknown   --       Types: Dark Ghost Ability: Pressure Held item: Leftovers Spiritomb♂ Lv.50 Spite Ghost Status   --       Double Team Normal Status   --       Unknown Unknown   --       Unknown Unknown   --