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These are my predictions for the main characters' teams in the anime!
I just think that Chimchar will evolve. Once. Yeah, yeah, I know, everyone wants Chimchar to evolve ALL THE WAY, but save that for the BF.
I think Piplup will FINALLY evolve (It's LOOOOOOONG overdue), as will Buneary after giving up on Pikachu.
Jessie FINALLY lets Seviper go.
James gets an over-affectionate Slugma!
For the BF, Ash leaves Gliscor, Grotle, and Buizel at Oak's and takes along Corphish. He subequently captures a Carvanha. By the third Facility, Corphish evolves into a Crawdaunt, and shortly afterwards, Monferno also evolves! Yay!
Dawn recieves an Eevee after leaving Pachirisu at home, and near the end of the BF, Eevee evolves into a Leafeon, possibly in Ilex Forest. She catches a Snubbull, which quickly evolves into a Granbull.
Jessie gets her Lickitung back, and one episode later, it evolves.
James gets his Cacnea, now a Cacturne, back. Slugma eveolves.